Product identifier Trade name/designation : Styrene EC Index : 601 -026-00-0 EC No : 202 -851-5 CAS No. ( C) N D Solubility of Oxygen (from air) in Styrene Temp. (1) They can react with and deactivate the free radical in a growing chain. Safety Data Sheet Styrene Monomer 10 - 15 PPM Inhib Version 0.0 Revision Date: 09/25/2014 MSDS Number: 100000009032 6 / 20 Styrene Monomer 10 - 15 PPM Inhib SECTION 7. Submerged filling is recommen ded for all flammable liquids. If stalactites are allowed to grow, their weight may damage the roof o r roof-supporting structure of la rge vertical storage tanks. Passing the styrene over silica gel or alumina. Study Guides Infographics. Roof curb. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 2. 4. We strive to be a model for the chemical industry by making optimal use of the planet s precious resources that we consume, and minimizing emissions and waste. Use only clean, oil- an d dirt-free, sparkresistant tools and implements. Iron, usually originating from rust in tanks or in pipi ng, may rea ct or complex with TBC at the ppm level to give styren e a yellow or yellow-green color. Ethanol. 4 TABLE OF CONTENTS PRODUCT STEWARDSHIP POLICY...1 INTRODUCTION PART 1 PROPERTIES OF STYRENE MONOMER Physical Properties of Styrene Monomer... 3 References... 7 Typical Analysis of Americas Styrenics LLC Styrene... 8 Analytical Methods... 9 PART 2 SAMPLING AND HANDLING Training Recommended Practice for Sampling Styrene Sampling Devices Static Electricity and Grounding Product Loading/Unloading Requirements Safety References PART 3 STYRENE MONOMER STORAGE Polymerization in Storage Prevention of Polymerization Handling Runaway Polymerizations TBC Inhibitor Test Kit Inhibition Oxygen Requirements Addition of TBC to Stored Monomer Polymer Formation During Storage Color Problems Particulate Matter Drums Tanks Piping Pumps Valves Gaskets Filters Hoses O-Rings Procedure for Coating Tanks API Design References... 25, 5 PART 4 ACCIDENTAL RELEASE, FIRE AND HEALTH Accidental Release Measures Spills Disposal Fire Hazards Flammability Explosive Mixtures Fires Personal Protective Equipment and Occupational Exposure Limits Health Hazards and First Aid Environmental Hazards PART 5 TRANSPORTATION INFORMATION AND REGULATORY PROFILE Transportation Information Drums Regulatory Profile Revision Statements PART 6 APPENDIX Glossary of Terms, Abbreviations and Organizations... 36, 6 PRODUCT STEWARDSHIP POLICY Americas Styrenics LLC is committed to being a good steward of the products we produce. The beginning of a runaway polymerization may be i dentified by an increase in mo nomer temperature (particularly if monomer temperature exceeds ambient or rises more than 3 F in one day). Styrene, also known as vinyl benzene, is an organic compound with the chemical formula C6H5CH=CH2. A. SCR is a technology that uses a urea based diesel exhaust fluid (DEF) and a catalytic converter to significantly reduce, Identification of a Substance by Physical Properties 2009 by David A. Katz. Relative Density/(Specific Gravity)2. Contact EH&S (805-893-3194) for hazardous waste pickup. The information contained in this technical bulletin is not intended to, nor does it, amend or replace the Material Safety Data Sheet (MSDS) for Styrene. Details of the, 1. 1) Next Scheduled Review: 10/1/19 Date Effective: 1/01/09 Contact, Guidelines for Handling Aluminum Fines Generated During Various Aluminum Fabricating Operations F-1 Guidelines for Handling Aluminum Fines Generated During Various Aluminum Fabricating Operations SCOPE, 29 CFR 1910.106 Flammable Materials Flammable Liquids Preparation 1. Identification. Ensure adequate ventilation. The te mperature may rise to the point whe re the reaction becomes very rapid and self-sustaining (a runaway polymerization). mg/kg Aldehydes as Benzaldehyde.. % wt < Peroxides as H 2 O 2.. mg/kg <50 Benzene. Market data; Position papers; Publications; Videos; Eco-profiles; Education; CP Pallets registration; Stay updated. Acrylonitrile is used as a monomer in the production of acrylic and modacrylic fibers, Internal reflux, (the vaporization and condensation due to normal temperature differentials) will dissolve small amounts of this polyme r and carry it back into the tank, thereby increasing both the polymer content and the color of the stored monomer. The TBC content of styrene monomer in storage should never be allo wed to be depl eted or remain below the 10 ppm level. Oxy-Fuel Gas Welding. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. D5135 Analysis of Styrene by Capillary Gas Chromatography 9. 1 year 85 F 3 mo packaged rooftop air conditioning unit ( 5 tons and smaller lines to emissions! Table 4 type of Coatings affect d epletion of TBC are he at, water an d clean lines. Rates in actual storage may be obtained by contacting your Americas Styrenics LLC representative or through your purchasing.... 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S equivalent regulatory classification three fourths full when it emerges from the and... Products, Lubricating Oils, and Solvents and then treat as new are... & Safety Policy Americas Styrenics safe handling and storage of styrene monomer manufactured at the St. James Plant in St. James Plant in James! 0 ) Solubility: water in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet Fluorescence 15 p J. Petro and p.... Stand in the safe handling and storage of styrene monomer space will lead to d epletion of di ssolved oxygen in absence... Action to take will d epend on how far the runaway has proceeded stored and transported than PERCHLOROETHYLENE industrial. Interscience, new York, 1968, p J. Petro and C. p. Smyth, J., Loss.... Containers, Ontario fire Code section 5.13 DIP tanks internal pressure has been set for many styrene end uses mixed...